The role of edge-driven convection in the generation ofvolcanism – Part 2: Interaction with mantle plumes, applied to the Canary Islands

In the eastern Atlantic Ocean, several volcanic archipelagos are located close to the margin of the African continent. This configuration has inspired previous studies to suggest an important role of edge-driven convection (EDC) in the generation of intraplate magmatism. In a companion paper (Manjón-Cabeza Córdoba and Ballmer, 2021), we showed that EDC alone is insufficient to sustain magmatism of the magnitude required to match the volume of these islands. However, we also found that EDC readily develops near a step of lithospheric thickness, such as the oceanic–continental transition (“edge”) along the western African cratonic margin. In this work, we carry out 3D numerical models of mantle flow and melting to explore the possible interactions between EDC and mantle plumes. We find that the stem of a plume that rises close to a lithospheric edge is significantly deflected ocean-ward (i.e., away from the edge). The pancake of ponding hot material at the base of the lithosphere is also deflected by the EDC convection cell (either away or towards the edge). The amount of magmatism and plume deflection depends on the initial geometric configuration, i.e., the distance of the plume from the edge. Plume buoyancy flux and temperature also control the amount of magmatism, and influence the style and extent of plume–EDC interaction. Finally, comparison of model predictions with observations reveals that the Canary plume may be significantly affected and deflected by EDC, accounting for widespread and coeval volcanic activity. Our work shows that many of the peculiar characteristics of eastern Atlantic volcanism are compatible with mantle plume theory once the effects of EDC on plume flow are considered.</p

Influence of material and haptic design on the mechanical stability of intraocular lenses by means of finite-element modeling

Intraocular lenses (IOLs) are used in the cataract treatment for surgical replacement of the opacified crystalline lens. Before being implanted they have to pass the strict quality control to guarantee a good biomechanical stability inside the capsular bag, avoiding the rotation, and to provide a good optical quality. The goal of this study was to investigate the influence of the material and haptic design on the behavior of the IOLs under dynamic compression condition. For this purpose, the strain-stress characteristics of the hydrophobic and hydrophilic materials were estimated experimentally. Next, these data were used as the input for a finite-element model (FEM) to analyze the stability of different IOL haptic designs, according to the procedure described by the ISO standards. Finally, the simulations of the effect of IOL tilt and decentration on the optical performance were performed in an eye model using a ray-tracing software. The results suggest the major importance of the haptic design rather than the material on the postoperative behavior of an IOL. FEM appears to be a powerful tool for numerical studies of the biomechanical properties of IOLs and it allows one to help in the design phase to the manufacturers

Hyperbolic subdiffusive impedance

We use the hyperbolic subdiffusion equation with fractional time derivatives (the generalized Cattaneo equation) to study the transport process of electrolytes in media where subdiffusion occurs. In this model the flux is delayed in a non-zero time with respect to the concentration gradient. In particular, we obtain the formula of electrochemical subdiffusive impedance of a spatially limited sample in the limit of large and of small pulsation of the electric field. The boundary condition at the external wall of the sample are taken in the general form as a linear combination of subdiffusive flux and concentration of the transported particles. We also discuss the influence of the equation parameters (the subdiffusion parameter and the delay time) on the Nyquist impedance plots.Comment: 10 pages, 5 figure

New multifunctional sulfonato-containing metal phosphonates proton conductors

Anchoring of acidic functional groups to organic linkers acting as ligands in metal phosphonates has been demonstrate to be a valid strategy to develop new proton conductor materials, which exhibit tunable properties and are potentially applicable to proton exchange membranes, such as those used in PEMFCs [1,2]. In this work, the structural and proton conductivity properties of several families of divalent and trivalent metal amino-sulfophosphonates are presented. The chosen ligand, (H2O3PCH2)2-N-(CH2)2-SO3H, was reacted with the appropriate metal salt using highthrough-put screening and/or microwave-assisted synthesis. Different crystal structures haven been solved displaying a variety of metal ligand coordination modes, in whose frameworks acidic groups contribute to create strong H-bond networks; together with lattice and bound water molecules. Proton conductivity values oscillate between 10-4 and 10-2 S.cm-1, at 80 ºC and 95 % relative humidity, most of them showing activation energies characteristic of a Grotthuss-type proton transport mechanism.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech. MINECO: MAT2016-77648-R Junta de Andalucía: P-12-FQM-1656 y FQM-11

Application of Solar Heating on the Electrolyte Conditioning for Electrowinning Process: Thermosolar Plant Performance

2013 ISES Solar World CongressIn this contribution the performance of a thermosolar plant to provide heat to the copper electrowinning (EW) process is analyzed. This plant has a collecting area of 404 m2 with flat plate solar collectors, and generation capacity of 540 MWht/year. It has a thermal storage tank where water can be stored at an average temperature of 95 °C. This allows providing continuously the energy to heat the electrolyte. It was determined the performance of the solar field and global performance of the plant for a working period of 4 months at the northern region conditions from Chile. In addition, the fuel consumption reduction for replacing liquefied gas by thermal solar energy to heat the electrolyte and CO2 emissions reduction were analyzed

NIRS potential use for the determination of natural resources quality from dehesa (acorn and grass) in Montanera system for Iberian pigs.

NIRS technology has been used as an alternative to conventional methods to determinate the content of nutrients of acorns and grass from dehesa ecosystem. Dry matter (DM), crude fat (CF), crude protein (CP), starch, total phenolic compounds (TP), α-tocopherol, γ-tocopherol, fatty acids, neutral detergent fiber (NDF), total antioxidant activity (TAA) and total energy (TE) were determined by conventional methods for later development of NIRS predictive equations. The NIR spectrum of each sample was collected and for all studied parameters, a predictive model was obtained and external validated. Good prediction equations were obtained for moisture, crude fat, crude protein, total energy and γ-tocopherol in acorns samples, with high coefficients of correlation (1-VR) and low standard error of prediction (SEP) (1-VR=0.81, SEP=2.62; 1-VR=0.92, SEP=0.54; 1-VR=0.86, SEP=0.47; 1-VR=0.84, SEP=0.2; 1-VR=0.88, SEP=5.4, respectively) and crude protein, NDF, α-tocopherol and linolenic acid content in grass samples (1-VR=0.9, SEP=1.99; 1-VR=0.87, SEP=4.13; 1-VR=0.76, SEP=10.9; 1-VR=0.82, SEP=0.6, respectively). Therefore, these prediction models could be used to determinate the nutritional composition of Montanera natural resources

Soc-based in-cycle load identification of induction heating appliances

The equivalent load of an induction hob is strongly dependent on many parameters such as the switching frequency, the excitation level and the size, type, and material of the vessel. However, real-time methods with the ability to capture the variation of the load with the excitation level have not been proposed in the literature. This is an essential issue as most of the commercial induction hobs are based on an ac-bus voltage arrangement. This article proposes a method based on a phase-sensitive detector that offers an online tracking of the equivalent impedance for this type of arrangements. This algorithm enables advanced control functionalities such as clustering of vessels, material recognition, and premature detection of ferromagnetic saturation, among others. After simulation and experimental validation, the method is implemented into a prototype with a system-on-chip to verify its real-time behavior. The proposed approach is applied to different real-life situations that prove its great performance and applicability